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Beilstein J. Org. Chem. 2014, 10, 969–974, doi:10.3762/bjoc.10.95
Graphical Abstract
Figure 1: Decarboxylative aldol reactions of β-keto acids with aldehydes.
Figure 2: Nucleophilic reaction of α-keto esters to generate tertiary alcohols.
Figure 3: Decarboxylative aldol reactions of β-keto acids with α-keto esters.
Scheme 1: Asymmetric decarboxylative aldol reaction of various β-keto acids with α-keto esters under optimise...
Scheme 2: Proposed mechanism of decarboxylative aldol reaction.